Zaldo C., Cano-Torres J.M., Álvarez-Pérez J.O., Han X.
Journal of Alloys and Compounds
To increase the Yb3+ optical bandwidths in highly anisotropic ß:KY(WO4)2 (KYW) type laser single crystals, the simultaneous contributions of the Bi3+ 6 s2 lone electron pair and Y3+/Bi3+ ionic radii mismatch is proposed. The top seeded solution growth method with K2W2O7 as solvent was used to grow Yb doped single crystals of the KY(WO4)2/KBi(WO4)2 (KYBiW) solid solution. Crystals obtained across the used KY1xBixW solid solution range show always the low temperature ß phase, with the monoclinic C2/c crystalline structure, but important differences between the Y/Bi composition of the starting solute and that of the crystal grown are found. The incorporation of Y and Yb into the crystal is preferential, resulting in a low Bi segregation coefficient, SBi= 13%, on the KYW side but near SBi= 90% in the KBiW side (Yb is still strongly incorporated filling the remaining 10%). The saturation temperature of the melt decreases as the Bi concentration in the precursor KY1-x-yBixYby(WO4)2/K2W2O7 mixture increases. Evidence of optical absorption and photoluminescence broadening of the Yb3+ bands with Bi3+ incorporation is derived from 6 K and 300 K measurements. Laser operation of KY1-x-yBixYby(WO4)2 crystals is shown to be comparable to that of KY1-yYby(WO4)2 ones. Up to ˜ 0.5 W of output power is obtained pumping in continuous wave regime with a Ti sapphire laser with slope efficiency <U+03B7> ˜ 65% and pump threshold< 200 mW, which is within the usual performance of KYW:Yb crystals, but the spectral distribution of the laser output in KYBiW:Yb crystals is larger than that for KYW:Yb. This spectral broadening may help in the reduction of ultrashort (fs) laser pulse duration generated by modelocking. © 2023 The Author(s)
