Seminars and Events
Materials Science Factory
05 October 2018, 12:00 h. Sala de Seminarios, 182
Tracking a cell’s mass in real time: a new indicator of cell physiology
Eidgenössische Technische Hochschule (ETH) Zurich, Switzerland
Regulation of cell volume and mass is physiologically important for living organisms and dysregulation of these parameters is at the origin of many different diseases. Cell mass mainly comprises intracellular water, proteins, lipids, carbohydrates and nucleic acids and is tightly liked to metabolism, proliferation and gene expression. However, the mechanisms that regulate cell mass remain largely unknown.
Flow cytometers and Coulter devices are among the most commonly used technologies to characterize the volume of suspended cells. However, most mammalian cells are adherent and behave considerably different in the suspended and adherent state. Therefore, one should be able to determine the volume and/or mass in the adherent state. Over the recent years powerful technologies have emerged to track the mass of single suspended and adherent cells. However, it has not been possible to track individual adherent cells in physiological conditions at the mass and time resolution required to observe fast cellular dynamics.
I will introduce a picobalance that we have developed, which is based on an optically excited microresonator. It measures the mass of single or multiple adherent cells in culture conditions over days at millisecond time resolution and picogram (0.1% of cell mass) mass sensitivity. I will also present some results we have obtained using this technology, including the detection of fast and subtle mass fluctuations that seem to be universal to living mammalian cells. Our approach is easy to operate and compatible with state-of-the-art optical microscopies, therefore we anticipate it will contribute to the understanding of cell mass regulation.
19 July 2018, 12:00 h. Sala de Seminarios, 182
Diseño, Preparación y Evaluación de Nuevas Mezclas Eutécticas y Acuosas Para la Síntesis de Materiales Mediante Procesos de Química Verde
Sara García Argüelles
Dpto. de Nuevas Arquitecturas en Ciencia de Materiales
Supervisor(s): Francisco del Monte
María Concepción Gutiérrez
En cualquier proceso sintético enfocado a la obtención de materiales es preciso controlar tres parámetros fundamentales, que determinarán el éxito de dicha síntesis en términos de rendimiento, selectividad, morfología y/o funcionalidad. Estos tres parámetros son: precursores, catalizadores y agentes directores de estructura de los materiales.
Parte de los trabajos experimentales realizados durante esta tesis están basados en el uso de mezclas eutécticas (DESs) -una categoría especial dentro de los líquidos iónicos- que se definen de forma genérica como fluidos compuestos por dos o tres componentes que son capaces de auto-asociarse, dando lugar una mezcla con un punto de fusión más bajo que el de sus componentes por separado. En estos trabajos se describe el diseño y la evaluación de nuevos DESs para su aplicación como catalizadores bifuncionales, en ausencia de disolventes tradicionales, y también, se diseñan y preparan nuevos DESs “todo en uno” que actúan simultáneamente como precursores de polímero y suministradores de moléculas farmacológicamente activas, además de como el medio de reacción donde se desarrolla la policondensación.
Por otro lado, se recogen trabajos experimentales, utilizando la metodología ISISA o Autoensamblado Inducido por Segregación de Hielo, donde el hielo actúa como agente director de estructura en la síntesis de materiales. En este caso se evalúa el diseño y la preparación de nuevos scaffolds biocompatibles a partir de soluciones o suspensiones acuosas de distintos sustratos de naturaleza diversa, controlando los parámetros críticos que determinan su estructura y propiedades.
25 June 2018, 10:30 h. Sala de grados, módulo 8. Facultad de Ciencias. UAM
Characterization and decoupling of high-quality graphene grown by fullerene decomposition on Cu foils
Jon Azpeitia Urkia
Instituto de Ciencia de Materiales de Madrid, CSIC.
Supervisor(s): Carmen Munuera López y Paqui López Fagúndez
11 June 2018, 16:00 h. Salón de Actos
Omar M. Yaghi
Department of Chemistry, University of California, Berkeley, California, USA
Linking molecular building units by strong bonds to make crystalline extended structures (Reticular Chemistry) has given rise to metal–organic frameworks (MOFs) and covalent organic frameworks (COFs), thus bringing the precision and versatility of covalent chemistry beyond the atoms and molecules. The key advance in this regard has been the development of strategies to overcome the “crystallization problem”, and the use of metal-oxide clusters as secondary building units to impart unprecedented structural robustness, high surface area, and permanent porosity. To date, thousands of MOFs and COFs are made as crystalline materials. The molecular units thus reticulated become part of a new environment where they have (a) lower degrees of freedom because they are fixed into position within the framework; (b) well-defined spatial arrangements where their properties are influenced by the intricacies of the pores; and (c) ordered patterns onto which functional groups can be covalently attached to produce chemical complexity. The notion of covalent chemistry beyond molecules is further strengthened by the fact that covalent reactions can be carried out on such frameworks, with full retention of their crystallinity and porosity. MOFs are exemplars of how this chemistry has led to porosity with designed metrics and functionality, chemically-rich sequences of information within their frameworks, and well-defined mesoscopic constructs in which nanoMOFs enclose inorganic nanocrystals and give them new levels of spatial definition, stability, and functionality. The advent of COFs extends the field of organic chemistry beyond discrete molecules (0D) and polymers (1D) into “infinite” two and three dimensions. Molecular weaving, the mutual interlacing of long threads at the molecular level, was first accomplished in COF to make the true woven material. This discovery combines the porosity and robustness of frameworks with mechanically deformable and stretchable capability.
07 June 2018, 12:00 h. Sala de Seminarios, 182
On the nature of correlations in the insulating states of twisted bilayer graphene
Instituto de Ciencia de Materiales de Madrid ICMM-CSIC
The recently observed insulating and superconducting states upon doping a graphene bilayer with a small twist angle have created a lot of excitement in the scientific community[1,2]. The stacking misorientation creates a moiré pattern with a superlattice modulation corresponding to thousands of atoms per unit cell. The insulating states, arise when the charge per moiré cell is ± 2. Superconductivity emerges from one of these insulating states.
Understanding the nature of the insulating states is key to uncover the origin of the superconductivity. The filling at which the insulating character appears is consistent with the ones of a Mott insulator and suggests a posible relation with the physics of cuprate high-Tc superconductors.
In the seminar I will review some aspects of the experimental results and introduce the physics and properties of Mott insulators. Common wisdom about Mott insulators is generally built upon techniques which only take into account local correlations. We will see that the expectations including only local correlations are not compatible with the experimentally observed behaviour of the insulating states with temperature and magnetic field . I will then argue that including non-local correlations can reverse these predictions and discuss other possible consequences of non-local correlations.
 Cao et al, Nature 556, p. 80-84 (2018)
 Cao et al, Nature 556, p. 43-50 (2018)
 J.M. Pizarro, M.J. Calderón, E. Bascones, arXiv:1805.07303
31 May 2018, 12:00 h. Sala de Seminarios, 182
Spin-orbital interplay in iron superconductors
Instituto de Ciencia de Materiales de Madrid ICMM-CSIC
Iron superconductors were discovered 10 years ago giving rise to the second family of high temperature superconductors with unknown superconducting mechanism. Most undoped pnictides present columnar magnetism and a puzzling electronic nematic phase that upon doping or pressure become superconducting. Over these years the spin scenario has shown to be a strong candidate to explain the mechanism of antiferromagnetism, nematicity and superconductivity. Notably exception is FeSe lacking the magnetic phase and presenting a peculiar orbital ordering. This situation has motivated the orbital ordering scenario for FeSe. In our work, we have taken a different route: we have derived a low energy effective model– the orbital selective spin fluctuations (OSSF)- model that allows to address spin-orbital interplay. [1,2]
So far, with this model we have been able to give a mechanism to understand (i) the difference between magnetism and nematicity in pnictides and FeSe,  (ii) the odd orbital ordering observed in ARPES in FeSe  (iv) The enigmatic anisotropy of the superconducting gaps in FeSe revealed by STM and ARPES experiments (vi) the renormalization of the velocity and the scattering rate due to self-energy effects reflected in the resistivity anisotropy. 
 L. Fanfarillo, A. Cortijo, and B. Valenzuela, Phys. Rev. B 91, 214515 (2015)
 L. Fanfarillo, L. Benfatto, and B. Valenzuela, Phys. Rev. B 97, 121109(R) (2018).
 L. Fanfarillo, et al., Phys. Rev. B 94, 155138 (2016).
 L. Fanfarillo, B. Valenzuela, L. Benfatto, arXiv:1804.05800.
 R. Fernández, L. Fanfarillo, L. Benfatto, B. Valenzuela, arXiv:1804.07293.
17 May 2018, 12:00 h. Sala de Seminarios, 182
Excitonic Nanomaterials as Photonic Building Blocks: Understanding and Controlling the Flow of Energy
The excited state properties of nanoscale semiconductors are dominated by the dynamics of quantum confined electron-hole pairs known as excitons. Thanks to recent advances in the size and shape control of semiconductor nanomaterials, this confinement can now be tuned with high precision which has resulted in a rapidly expanding family of high-quality excitonic building blocks. However, while extensive research has been done to understand and control the excitonic properties of the isolated building blocks, comparatively little is known about exciton dynamics in nanoscale assemblies.
In the first part of the talk, I will present some of our efforts in trying to understand and control the exciton dynamics in nanomaterial assemblies. Specifically, I will discuss transient microscopy techniques which allow us to spatially resolve exciton diffusion in colloidal quantum-dot films. In addition, I will present our findings of anomalous excitonic energy-transfer dynamics between zero-dimensional colloidal quantum-dots and two-dimensional MoS2 monolayers.
In the second part of the talk, I will present new strategies for the assembly of excitonic building blocks into high quality wavelength-scale patterns using template stripping of colloidal quantum-dot films. I will show that this technique can produce high-quality photonic structures composed solely out of colloidal quantum dots.
Finally, I will briefly highlight some recent work on the use of plasmonic antennas to structure the fluorescence of colloidal quantum-dot emitters, specifically by mapping spectral information to the polarization state of light. Based on this concept, we propose polarization-resolved spectroscopy scheme that may benefit high-speed readout of fluorescent signatures.
10 May 2018, 12:00 h. Sala de Seminarios, 182
Topological lasers and condensates
University of Lancaster
Topological photonics aims to replicate fermionic symmetries as feats of precision engineering. Here I show how to enhance these systems via effects such as gain, loss and nonlinearities that do not have a direct electronic counterpart. This leads to a topological mechanism of mode selection [1,2,3], formation of compactons in flat band condensates , and topological excitations in lasers when linearized around their working point . The resulting effects show a remarkable practical robustness against disorder, which arises from the increased spectral isolation of the manipulated states.
 Topologically protected midgap states in complex photonic lattices, H. Schomerus, Opt. Lett. 38, 1912 (2013).
 Selective enhancement of topologically induced interface states in a dielectric resonator chain, C. Poli, M. Bellec, U.Kuhl, F. Mortessagne, H. Schomerus, Nat. Commun. 6, 6710 (2015).
 Topological Hybrid Silicon Microlasers, H. Zhao et al., Nat. Commun. 9, 981 (2018)
 Exciton-polaritons in a two-dimensional Lieb lattice with spin-orbit coupling, C. E. Whittaker et al., Phys. Rev. Lett. 120, 097401 (2018)
 Topological phases in nonlinear complex-wave equations with a time-preserving symmetry, S. Malzard, E. Cancellieri, and H. Schomerus, arXiv:1705.06895
07 May 2018, 12:00 h. Sala de Seminarios, 182
Viscosity of 2D Topological Phases
One hallmark of topological phases with broken time reversal symmetry is the appearance of quantized non-dissipative transport coefficients, the archetypical example being the quantized Hall conductivity in quantum Hall states. Here I will talk about a new non-dissipative transport coefficients that appear in such systems - the Hall viscosity. In the first part of the talk, I will start by reviewing previous results concerning the Hall viscosity, including its relation to a topological invariant known as the shift when rotational symmetry is preserved. Next, I will show how the Hall viscosity can be computed from a Kubo formula. For Galilean invariant systems, the Kubo formula implies a relationship between the viscosity and conductivity tensors which may have relevance for experiment. In the second part of the talk, I will examine the fate of the Hall viscosity when rotational symmetry is broken. Through a combination of field theory and numerical techniques, I will show that rotational symmetry breaking allows for the introduction of a new topological quantum number characterizing quantum Hall states.
26 April 2018, 12:00 h. Sala de Seminarios, 182
Moiré patterns and spontaneous deformations in 2D crystals
Instituto de Ciencia de Materiales de Madrid ICMM-CSIC
Following recent reports of superconductivity and Mott transitions in twisted graphene bilayers, the field of moiré patterns in stacked 2D crystals has seen a surge of interest. I will review the rich phenomenology associated to moiré patterns in various heterostructures of 2D crystals, both from an electronic and from an elastic point of view. I will focus on the case of twisted graphene bilayer and graphene on hexagonal boron nitride. The elastic aspect of the problem, which has received comparatively little attention, will be analysed within a simple continuum description. This model is sufficient to capture the formation and properties of stacking solitons, which dramatically affect the electronic properties in some systems. It will also be employed to explain and the characteristic the spontaneous rippling of some van der Waals materials, such as Franckeite and Cylindrite, whose large scale structure is thus shown to be a consequence of interlayer moiré patterns.
19 April 2018, 12:00 h. Salón de Actos
The role of local correlations in the quasi-one dimensional iron superconductor BaFe2S3
José María Pizarro
Instituto de Ciencia de Materiales de Madrid ICMM-CSIC
In 2008, Hosono’s group discovered superconductivity in the iron-based superconductors. In this family, a quasi-2D layer is formed by arranging the iron atoms in a square pattern, with pnictogen or chalcogen atoms tetrahedrally coordinating these iron positions. The superconducting phase appears when a antiferromagnetic phase is supressed by doping or by applying pressure. Superconductivity is unconventional but its origin is not well established. The phase diagram of this family is similar to the one of cuprate superconductors. However, a striking difference is that the parent compound of iron superconductors is a metal in which the Hund’s coupling seems to play an important role, while for the cuprates it is a Mott insulator. The metallic nature of the iron superconductors has led to a never ending debate about the role of local correlations on superconductivity.
In 2015 a new kind of iron superconductor with a quasi-one dimensional two leg ladder structure was discovered. BaFe2S3 becomes superconductor with T_c^max≈24K when pressure is applied ≈10GPa and an antiferromagnetic phase is supressed. In 2017, another related compound, BaFe2Se3, was also reported to be a superconductor with T_c^max≈11Kat ≈12.7GPa. Interestingly, at zero pressure these systems are insulators, and what has led some authors to propose that they are Mott insulators.
In this talk I will briefly review some of the phenomenology of iron superconductors, as well as the Hund metal paradigm. In the main part, I will present the calculations that we have performed to clarify the role of electronic interactions in the superconductor BaFe2S3.
05 April 2018, 12:00 h. Salón de Actos
Spin-Orbit Coupling at the interfaces: a great spin-to-charge converter
Universidad del País Vasco
The inversion symmetry breaking at the interface between different materials generates strong spin-orbit coupling (SOC). We will study through theoretical models various transport phenomena in metal-metal and metal-oxide and ferromagnet-oxide junctions induced by this interaction. This type of interaction is responsible of the greatest spin-to-charge conversion. We will show that apart from this spin-to-charge conversion this SOC is also responsible of spin swapping, (spin-to-spin conversion) and anomalous Hall effects in the presence of ferromagnetic materials.
02 March 2018, 10:30 h. Sala de Seminarios, 182
Quantum dots and superconductivity in silicon systems
University of Twente. The Netherlands.
Ge/Si core/shell nanowires are proposed candidates for observing Majorana fermions where a hard superconducting gap is essential for topological protection at zero energy. In double quantum dots, we observe shell filling of new orbitals and corresponding Pauli spin blockade. In nanowires with superconducting Al leads we create a Josephson junction via proximity-induced superconductivity. A gate-tuneable supercurrent is observed with a maximum of ~60 nA. We identify two different regimes: Cooper pair tunnelling via multiple subbands in the open regime and, while near depletion a supercurrent is carried by single-particle levels of a quantum dot operating in the few-hole regime.
Secondly, we create ambipolar quantum dots in silicon nanoMOSFETs. After passivation of charge defects we can electrostatically define hole quantum dots up to 180 nm in length. In recent devices, we have characterized the conformity of aluminium, titanium and palladium nanoscale gates by means of transmission electron microscopy (TEM). Subsequently, we have defined low-disorder quantum dots with Pd gates. Finally, we have made depletion-mode hole quantum dots in intrinsic silicon. We use fixed charge in a SiO2/Al2O3 dielectric stack to induce a 2DHG at the Si/SiO2 interface. This depletion-mode design avoids complex multilayer architectures requiring precision alignment and allows directly adopting best practices already developed for depletion dots in other material systems.
01 March 2018, 12:00 h. Sala de Seminarios, 182
Topological materials with smooth interfaces -- what one can learn from Landau-level quantization
Mark O. Goerbig
Laboratoire de Physique des Solides. Université Paris Saclay.
Motivated by experimental findings , we study theoretically smooth topological interfaces, i.e. interfaces between a topological and a normal insulator. In addition to the usual topologically protected chiral surface states, which do not depend on the specific form of the interface, several massive states appear if the interface width is larger than a particular intrinsic length (given by the bulk gap and the Fermi velocity). These states, first described by Volkov and Pankratov in the 1990ies , are intrinsically relativistic and can be related to Landau bands of relativistic fermions. We show that the gap variation can be interpreted precisely as a vector potential that is affected by an additional electric field in a relativistic manner . The electric field can thus be used not only to dope electronically these massive surface states, but they become even more accessible due to the reduction of the Landau gap in the presence of an electric field. The effect is at the origin of an oscillating resistance measured as a function of the electric field in high-frequency experiments . We finish with a short discussion of how this "Landau-level approach" can also be used in the framework of Weyl semimetals and the description of Fermi arcs that play the role of chiral Landau bands here 
 A.Inhofer et al. PRB 96, 195104 (2017)
 V.Volkov and O. Pankratov, JETP Lett 42, 178 (1985)
 S.Tchoumakov et al. PRB 96, 201302 (2017)
 S.Tchoumakov et al. PRB 95, 125306 (2017)
22 February 2018, 12:00 h. Sala de Seminarios, 182
Buckling, ripples and dynamical phenomena in suspended graphene
Universidad Carlos III
Recent scanning tunneling microscope (STM) experiments have shown that a soft rippled flat state coexists with a hard buckled state in suspended graphene sheets. For small values of the STM current, the transition between these states is reversible, whereas it becomes irreversible when the STM current surpasses a certain threshold. We present phenomenological models of graphene as a membrane coupled to pseudo-spins that undergo Glauber dynamics. These models allow us to understand the STM induced transitions between rippled flat and buckled states as driving the spin-membrane system through a first order phase transition.
15 February 2018, 12:00 h. Sala de Seminarios, 182
Non-local conductivity of 2D Dirac cones and Quantum friction with Unruh-deWitt detectors
Pablo Rodríguez López
Instituto de Ciencia de Materiales de Madrid ICMM-CSIC
This talk will be structured in two parts.
In the first part, we investigate the electromagnetic response of staggered two-dimensional materials of the graphene family, including graphene, silicene, germanene, and stanene, as they are driven through various topological phase transitions using external fields  . Utilizing Kubo formalism, we compute their optical conductivity tensor taking into account the frequency and wave vector of the electromagnetic excitations, and study its behavior over the full electronic phase diagram of the materials. We compute the Plasmon dispersion relation for different phases.
In the second part of the talk, we revisit the atom-plate quantum friction and Casimir force with a full-relativistic formalism for atoms modelled as Unruh-deWitt detectors in exited, relaxed and coherent superposition close to a plate . We show that, for relative velocities close to c, the quantum friction diverges while the Casimir force is almost independent of the velocity. We are able to include the effect of the finite size of the detector, then we also obtain quantum friction when the detector is isolated but follows a non-inertial trajectory and we obtain a more realistic result for short distance interactions.
Those studies open the venue to understand the role of non-local response in quantum friction.
 P. Rodriguez-Lopez, et al., Nature Communications 8, 14699 (2017)
 P. Rodriguez-Lopez, et al., Phys. Rev. Materials 2, 014003 (2018)
 P. Rodriguez-Lopez and E. Martin-Martinez. Casimir Forces and Quantum friction of finite-size atoms in relativistic trajectories. Submitted
06 February 2018, 12:00 h. Sala de Seminarios, 182
Near-field photonic mode mapping
Department of Physics and Astronomy, University of Florence, Italy
The tremendous progress in nanophotonics towards efficient quantum emitters at the nanoscale requires investigation tools able to access the detailed features of the electromagnetic field with deep-subwavelength spatial resolution. This scenario has motivated the development of different nanoscale photonic imaging techniques.
In this contribution, we will overview our activity in exploiting near-field microscopy for optical characterization of photonics nanoresonators, showing that the scanning near-field optical microscopy (SNOM) is a powerful method to image the electric-magnetic fields in nanophotonics.
We will discuss a novel technique involving the combination of scanning near-field optical microscopy with resonant scattering spectroscopy, leading to Fano profiles signal for the optical modes . By exploiting both tip perturbation and collection, either in forward or in backward geometry, our approach enables the imaging of the electric and magnetic field intensity (including phase, amplitude and polarization) in nano-resonators with sub-wavelength spatial resolution (Lambda/20) [1-4]. We will discuss results both in photonic crystals [1-4] and in disordered modes [5-8]. We conclude with recent results on the exploitation of our resonant scattering SNOM for addressing the exceptional points in photonics .
 N. Caselli, et al. Light: Science & Applications 4, e326 (2015)
 N. Caselli, et al. Scientific Reports 5, 9606 (2015)
 F. La China, et al. Appl. Phys. Lett. 107, 101110 (2015)
 F. La China, et al. ACS Photonics 2, 1712 (2015)
 F. Riboli, et al. Nat. Materials 13: 720 (2014)
 N. Caselli, et al. APL Photonics 1, 041301 (2016)
 N. Caselli, et al. APL 110, 081102 (2017)
 N. Caselli, et al. Nat. Comm. in press (2018)
01 February 2018, 12:00 h. Sala de Seminarios, 182
Charge localization in hybrid superconductor-semiconductor nanowire devices
Universidad Autónoma de Madrid
Hybrid devices that couple superconductors and semiconductor nanowires have attracted considerable attention in recent years owing to their potential to realize topological superconductivity and Majorana zero modes. The topological phase is predicted to result from a combination of induced superconductivity, spin-orbit coupling and spin polarization in the semiconductor nanowire. Crucially, the one-dimensional character of such a system must be preserved over micron-length scales for the topological phase to the established - a requirement that is not so straightforward to meet in realistic materials. In this talk, I will address experiments performed in InAs-based hybrid superconductor-semiconductor nanowire devices, in which clear signatures of charge localization are detected. I will discuss different effects associated with the resulting superconductor-quantum dot system whose signatures could be mistakenly interpreted in favor of Majorana zero modes. In particular, I will address zero-bias peaks related to the Kondo effect and the Zeeman splitting of Andreev levels. Finally, I will discuss how, even when seemingly absent, charge localization plays a crucial role in the transport properties of quasi-ballistic nanowire quantum point contacts.
18 January 2018, 12:00 h. Sala de Seminarios, 182
Topological π-junctions from crossed Andreev reflection in the Quantum Hall regime
Instituto de Ciencia de Materiales de Madrid ICMM-CSIC and IMDEA Nanociencia
In this talk I will review some of the current achievements in the pursuit of Majorana fermions, along with the major drawbacks that stand in the way of exploiting them as fundamental qubits in the field of topological quantum computation. I will introduce a novel setting for creating Majorana bound states and performing protected non-Abelian single-qubit operations without real space braiding of Majoranas and with no fine-tuning of the control parameters. The proposed platform is a two-dimensional electron gas in the Quantum Hall regime in the presence of a Zeeman field, with the Fermi level tuned to filling factor 1. I will show that, in the presence of spin-orbit coupling, contacting the 2DEG to a narrow strip of an s-wave superconductor produces a topological superconducting gap along the contact as a result of crossed Andreev reflection processes across the strip. The sign of the topological gap depends periodically on the Fermi wavelength and strip width and can be externally tuned. An interface between two halves of a long strip with topological gaps of opposite sign implements a robust π-junction that hosts a pair of protected Majorana zero modes. Such a configuration can be exploited to perform non-Abelian tunnel-braid operations that are much simpler to execute than Majorana braidings in real space, and are nevertheless topologically protected.
16 January 2018, 12:00 h. Sala de Seminarios, 182
Characterization of organic self-assembled monolayers using bimodal
Atomic Force Microscopy
École Polytechnique Fédérale de Lausanne, Switzerland
Self-assembled monolayers (SAMs) are one of the most attractive methods of surface modification, as they are highly versatile and their manufacturing approach is easy to scale up. One of their key features is molecular ordering, which, however, is difficult to determine experimentally.
Bimodal AFM was used as a novel approach for the characterization of SAMs’ ordering, via its correlation to surface elasticity.
Alkanethiol SAMs on Au (111) were used as a model system. Surface elasticity has been reliably determined and found to be ligand-length dependent. A similar investigation has been extended to the characterization of octadecylphosphonic acid SAMs on Al2O3. Monolayer formation and ordering as a function of formation time were determined via surface elasticity.
The characterization method was then extended to provide localization of the chemical
species present in thiolated binary SAMs. Within the systems tested phase separation down to ~10 nm domains could be observed both in the topography and in the elasticity channel, allowing, for the first time, the chemical identification of the domains.
11 January 2018, 12:00 h. Sala de Seminarios, 182
Graphene on rhodium from first principles: Tailoring electronic, structural and chemical properties
Carlos Romero Muñiz
Universidad Autónoma de Madrid
We demonstrate the possibility of modeling recent experiments in complex graphene-metal (G-M) systems by means of Density Functional Theory (DFT) calculations. Since different modification techniques are currently applied on G -and related materials- to get new functionalities, our work does not restrict to the mere description of the G-M interface but we have to reproduce all these surface modifications. More precisely, we reveal the multi-domain structure of G grown on Rh(111), an archetypical strongly interacting substrate, in which G adopts a rippled structure with corrugations larger than 1 Å . Additionally, we will present different examples of surface modification; like the evolution of G properties as a function of the oxygen coverage in the interface ; the atomistic mechanisms involved in this intercalation process ; and the tailoring of the electronic properties by means of ion implantation nitrogen doping [4,5]. Finally, we will briefly discuss about some methodological aspects of DFT calculations in this kind of G-M systems and their current limitations when dealing with very large systems (like grain boundaries, G-covered metallic steps or under-cover chemical reactions).To overcome this issue, we present preliminary results of a new approach based on highly optimized localized orbital basis set to reach high-accuracy descriptions at quantum level of systems with thousands of atoms.
 A. Martín-Recio et al. Nanoscale 7 (2015) 11300
 C. Romero-Muñiz et al. Carbon 101 (2016) 129
 C. Romero-Muñiz et al. (submitted)
 A. Martín-Recio et al. Nanoscale 8 (2016) 17686
 A. Martín-Recio et al. (submitted)